
Corrosion? Abrasion? About KF Polymer. KF Polymer coating powder provides a corrosion resistant protective coating of from .015 to .050 inches in thickness, impervious to a wide variety of corrosive environments up to 300 º F, and in addition has excellent mechanical properties, such as impact resistance.
KF Polymer is a flourocarbon
thermoplastic resin (PVF2, polyvinylidene flouride). It is available
in fluid bed grade and electrostatic grade for application with conventional
techniques.
Performance Characteristics
Chemical Resistance
KF Polymer has outstanding resistance to most in organic acids, alkalies, aliphatic and aromatic hydrocarbons, organic acids, alcohols, halogenated solvents, halogens and strong oxidizing agents.
Spool piece tests of over 11,000 hours in 36% Hydrochloric acid, 93.6% Sulfuric acid and 40% Nitric acid at a temperature of 71 º C (160 º F), at 150 psi pressure, showed no permeation or degradation of KF Polymer. A similar test of 9,000 hours in 36% Hydrochloric acid at a temperature of 104 º C (220 º F) also showed no permeation or degradation.
KF Polymer provides an excellent pin-hole free permeation barrier to small molecules. Access to a KF Polymer coated substrate by corrosives is effectively prevented. Water permeability of polyvinylidene flouride according to ASTM E-96 (gram) (mil) (100in²) (24h) (atm) at 25 º C (77 º F) is 1.56.
Hot fuming Sulfuric acid, some strong basic amines, hot concentrated alkalies and alkaline metals can cause degradation. Slight swelling may occur with use in highly polar solvents, such as acetone and ethyl acetate.
For more detailed information see Technical Data Sheet "KF Polymer--Chemical Resistance".
Physical Properties
KF Polymer has excellent bonding between molecules and shows good mechanical properties in elongation, flexure, tension, compression and impact.
The tensile yield strength is 575kg/cm² (8000 psi), the highest of any of the flourinated polymers. See graph below.

KF Polymer has a high heat distortion temperature. Creep resistance is good. At a stress of 140 kg/cm² and a temperature of 25 º C, the creep rate is 1.5%.
The use temperatures where KF Polymer can be used range from -20 º C (-4 º F) to 150 º C (302 º F). Thermal treatment, such as post-curing, can extend these limits from -60 º C (-76 º F) to 170 º C (338 º F).
Fire Resistance
In actual ASTM D 635 Tests, KF Polymer does not burn freely and self-extinguishes on removal of the flame. It has an oxygen index of 43 (minimum quantity of oxygen, expressed in %, in an atmosphere in which burning could occur), meaning KF will not burn in a normal atmosphere.
UV and Gamma Radiation Stability
Weathering and aging resistance are excellent. KF Polymer shows good gloss holding capacity against ultra-violet radiation. Weatherometer tests indicate no decrease in tensile strangth after exposure to ultraviolet radiation for 3,000 hours.
After exposure to 100 megarads of electromagnetic radiation, KF Polymer showed no decrease in tensile strength.
KF Polymer's stability under ulltraviolet and gamma radiation is unsurpassed by other plastics.
For more specific information on the Physical Properties of KF, see Table 1.
Food Processing Use
FDA. KF Polymer resin conforms to FDA requirements and may be safely used as articles or components of articles intended for use in contact with food. Use environments involving food acids and caustic cleaning at elevated temperatures can be handled. Requirements for food use may be found in the code of Federal Regulations, 21, Food and Drugs, Part 177.2510.
USDA. KF Polymer is chemically acceptable for application to surfaces where there is apossibility of incidental contact with meat or poultry food products prepared under Federal inspection.
It is also acceptable for use on those areas of equipment permitted to be coated in the standard for equipment design and construction published in "Accepted Meat and Poultry Equipment, MPI²".
Caution
KF Polymer is non-toxic in the polymeric state, however, its principal thermal decomposition product, hydrogen flouride, is toxic. Precautions should be taken to prevent inhalation and physical contact should inadvertent decomposition of KF Polymer occur. Waste KF Polymer or coated parts should not be incinerated without adequate fume disposal facilities.
| TABLE 1. SUMMARY OF PHYSICAL PROPERTIES | |||||
PROPERTY |
CONDITION |
UNIT |
METHOD (ASTM) |
KUREHA KF POLYMER |
|
Mechanical |
|||||
| Tensile strength | 23 C |
kg/cm2 |
D638 |
500 600 |
|
100 C |
kg/cm2 |
D638 |
200 300 |
||
| Elongation | 100 C |
% |
D638 |
200 300 |
|
| Compressive Strength | kg/cm2 |
D695 |
900 1000 |
||
| Flexual Strength | kg/cm2 |
D790 |
|||
| Tensile Modulus | 103 kg/cm2 |
D638 |
12 14 |
||
| Compressive Modulus | 103 kg/cm2 |
D695 |
10 14 |
||
| Flexural Modulus | 103 kg/cm2 |
D790 |
16 18 |
||
| Izod Impact Strength | Notched, ½" x ½" |
Ft. lb in of notch |
D256 |
1.8 2.2 |
|
| Rockwell Hardness | D785 |
R 110 |
|||
| Abrasion-Tabor Test Method | Abrasion Disk CS-17, Load 1kg |
mg/1000 cycles |
9.3 |
||
| Thermal |
|||||
| Thermal Conductivity | 10-4 cal/sec/cm2/1(ºC/cm) |
C177 |
3.0 |
||
| Specific Heat | Room Temp |
cal/ºC |
0.33 |
||
| Thermal Coefficient of Linear Expansion | 10-5/ºC |
D696 |
12 |
||
| Head Distortion Temp | 4.6kg/cm2 |
ºC |
D648 |
150 |
|
18.5kg/cm2 |
ºC |
D648 |
98 |
||
Electrical |
|||||
| Volume Resistivity | 50%RH/23ºC |
ohm-cm |
D257 |
3~6x1014 |
|
| Dielectric Strength | Short Time, 3.18mm |
KV/mm |
D149 |
10 |
|
| Dielectric Constant | 60Hz |
D150 |
9.8 |
||
103Hz |
9.5 |
||||
106Hz |
7.5 |
||||
| Dissipation Factor | 60Hz |
D150 |
0.05 |
||
103Hz |
0.018 |
||||
106Hz |
0.16 |
||||
Other Properties |
|||||
| Specific Gravity | D792 |
1.76 1.77 |
|||
| Water Absorption | 24hrs, 3.18mm |
% |
D570 |
0.03 |
|
| Melting Point | ºC |
185 |
|||
| Decomposition Temperature | ºC |
350 |
|||
| Crystallization Temperature | ºC |
140 |
|||
| Flammability | D635 |
Self-extinguishing |
|||